N-(2-ADAMANTYL)-N-(4-BROMOPHENYL)AMINE

  • CAS:87913-26-6
  • MF:C16H20BrN
  • Purity:99%
  • Molecular Weight:306.245
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Product Details

  • CAS: 87913-26-6
  • MF: C16H20BrN
  • Reputable supplier selling N-(2-ADAMANTYL)-N-(4-BROMOPHENYL)AMINE 87913-26-6 with stock

    • Molecular Formula:C16H20BrN
    • Molecular Weight:306.245
    • Boiling Point:404.8 °C at 760 mmHg 
    • PKA:3.97±0.20(Predicted) 
    • Flash Point:198.6 °C 
    • PSA:12.03000 
    • Density:1.388 g/cm3 
    • LogP:4.75870 

    87913-26-6 Relevant articles

    Anthracene-rhodium complexes with metal coordination at the central ring-a new class of catalysts for reductive amination

    Kuchuk, Ekaterina,Muratov, Karim,Perekalin, Dmitry S.,Chusov, Denis

    supporting information, p. 83 - 87 (2019/01/04)

    A new class of anthracene complexes with...

    Ruthenium-catalyzed reductive amination without an external hydrogen source

    Kolesnikov, Pavel N.,Yagafarov, Niyaz Z.,Usanov, Dmitry L.,Maleev, Victor I.,Chusov, Denis

    supporting information, p. 173 - 175 (2015/01/30)

    A ruthenium-catalyzed reductive aminatio...

    Palladium-catalyzed amination of isomeric dihalobenzenes with 1- and 2-aminoadamantanes

    Averin,Ulanovskaya,Kovalev,Buryak,Orlinson,Novakov,Beletskaya

    experimental part, p. 64 - 72 (2010/06/19)

    Palladium-catalyzed amination of isomeri...

    87913-26-6 Process route

    2-Adamantanone
    700-58-3

    2-Adamantanone

    4-bromo-aniline
    106-40-1

    4-bromo-aniline

    N-(4-bromophenyl)adamantan-2-amine
    87913-26-6

    N-(4-bromophenyl)adamantan-2-amine

    Conditions
    Conditions Yield
    With rhodium(III) chloride hydrate; carbon monoxide; In acetonitrile; at 140 ℃; for 11h; Autoclave; Molecular sieve;
    90%
    With carbon monoxide; [(η4-cyclooctadiene)Rh(η6-2,3,6,7-tetramethoxy-9,10-dimethylanthracene)]BF4 ; In tert-butyl alcohol; at 120 ℃; for 24h; under 7600.51 - 38002.6 Torr; Autoclave;
    70%
    1.4-dibromobenzene
    106-37-6

    1.4-dibromobenzene

    N-(2-adamantyl)amine
    13074-39-0

    N-(2-adamantyl)amine

    N-(4-bromophenyl)adamantan-2-amine
    87913-26-6

    N-(4-bromophenyl)adamantan-2-amine

    Conditions
    Conditions Yield
    With 2,2'-bis-(diphenylphosphino)-1,1'-binaphthyl; bis(dibenzylideneacetone)-palladium(0); sodium t-butanolate; In 1,4-dioxane; for 7h; Reflux; Under argon;
    57%

    87913-26-6 Upstream products

    • 106-37-6
      106-37-6

      1.4-dibromobenzene

    • 13074-39-0
      13074-39-0

      N-(2-adamantyl)amine

    • 700-58-3
      700-58-3

      2-Adamantanone

    • 106-40-1
      106-40-1

      4-bromo-aniline

    Antioxidant BHT 264

    CAS:128-37-0

    Purity:99%

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