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Lithium aluminium hydride is white crystalline powder, while it's Molecular Formula is AlH4.Li. Lithium aluminum hydride is among the most important industrial reducingagents. It is used extensively in organic syntheses and also in catalytichydrogenation. Reactant or reagent for: 1. The preparation of thermoplastic polyester polyamides from oleic acid 2. Lithium-polymer batteries 3. Hydrodefluorination of gem-difluoromethylene derivatives 4. Asymmetric aldol reactions 5. Synthesis of Li-Al-N-H composites with hydrogen absorption / desorption properties 6. LAH is a powerful reducing agent for many different reduction reactions such as that of ketones to alcohols
The CAS number of Lithium aluminium hydride is 16853-85-3.
More information of Lithium aluminium hydride 16853-85-3 are:
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Synonyms |
Aluminate(1-),tetrahydro-, lithium (8CI);Aluminate(1-), tetrahydro-, lithium, (T-4)- (9CI);Aluminum lithium hydride (LiAlH4) (6CI);Aluminum lithium tetrahydride;Lithiumalanate;Lithium aluminum hydride (LiAlH4);Lithiumaluminum tetrahydride;Lithium tetrahydridoaluminate;Lithiumtetrahydroaluminate;Lithium tetrahydroaluminate (AlLiH4);Lithiumtetrahydroaluminate(1-); |
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CAS Number |
16853-85-3 |
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Molecular Formula |
AlH4.Li |
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Molecular Weight |
37.9543 |
|
Density |
0.917 |
|
Melting Point |
125 °C (dec.)(lit.) |
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Boiling Point |
0 °C |
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Flash Point |
99 °F |
|
HS CODE |
2850 00 20 |
|
PSA |
0.00000 |
|
LogP |
0.45000 |
Lithium aluminum hydride (LiAlH4) is a promising compound for hydrogen storage, with a high gravimetric and volumetric hydrogen density and a low decomposition temperature. Similar to other metastable hydrides, LiAlH4 does not form by direct hydrogenation at reasonable hydrogen pressures; therefore, there is considerable interest in developing new routes to regenerate the material from the dehydrogenated products LiH and Al. It can also be used as a reducing agent in the preparation of reduced graphene oxide (rGO).
InChI:InChI=1/Al.Li.4H/q-1;+1;;;;/rAlH4.Li/h1H4;/q-1;+1
Articles related to Lithium aluminium hydride:
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Article |
Source |
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- |
, (1984) |
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Ionic liquids as an efficient medium for the mechanochemical synthesis of α-AlH3 nano-composites |
Duan,Hu,Ma , p. 6309 - 6318 (2018) |
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