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2-Bromo-spiro[9H-fluorene-9,9'-[9H]xanthene]

  • CAS:899422-06-1
  • MF:C25H15BrO
  • Purity:99%
  • Molecular Weight:411.297
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Product Details

  • CAS: 899422-06-1
  • MF: C25H15BrO
  • Excellent chemical plant bulk supply 2-Bromo-spiro[9H-fluorene-9,9'-[9H]xanthene] 899422-06-1

    • Molecular Formula:C25H15BrO
    • Molecular Weight:411.297
    • Melting Point:255 °C 
    • Boiling Point:513.8±39.0 °C(Predicted) 
    • PSA:9.23000 
    • Density:1.54±0.1 g/cm3(Predicted) 
    • LogP:6.91790 

    899422-06-1 Relevant articles

    A Yellow-Emitting Homoleptic Iridium(III) Complex Constructed from a Multifunctional Spiro Ligand for Highly Efficient Phosphorescent Organic Light-Emitting Diodes

    Ren, Bao-Yi,Guo, Run-Da,Zhong, Dao-Kun,Ou, Chang-Jin,Xiong, Gang,Zhao, Xiang-Hua,Sun, Ya-Guang,Jurow, Matthew,Kang, Jun,Zhao, Yi,Li, Sheng-Biao,You, Li-Xin,Wang, Lin-Wang,Liu, Yi,Huang, Wei

    , p. 8397 - 8407 (2017)

    To suppress concentration quenching and ...

    Carbazole-endcapped Spiro[fluorene-9,9′-xanthene] with Large Steric Hindrance as Hole-transporting Host for Heavily-doped and High Performance OLEDs

    Zhao, Xianghua,Wu, Yukun,Shi, Nannan,Li, Xiaoyu,Zhao, Yi,Sun, Mingli,Ding, Dongxue,Xu, Hui,Xie, Linghai

    , p. 955 - 960 (2015)

    In this work, we designed and synthesize...

    Nondoped deep-blue spirofluorenexanthene-based green organic semiconductors (GOS) via a pot, atom and step economic (PASE) route combining direct arylation with tandem reaction

    Sun, Ming-Li,Zhu, Wen-Sai,Zhang, Zhen-Song,Ou, Chang-Jin,Xie, Ling-Hai,Yang, Yang,Qian, Yan,Zhao, Yi,Huang, Wei

    , p. 94 - 99 (2015)

    Effective synthesis of organic semicondu...

    NOVEL HETEROCYCLIC COMPOUND AND ORGANIC LIGHT EMITTING DEVICE COMPRISING THE SAME

    -

    Paragraph 0113-0115, (2020/08/30)

    Provided is a novel heterocyclic compoun...

    DELAYED FLUORESCENT COMPOUND, AND ORGANIC LIGHT EMITTING DIODE AND ORGANIC LIGHT EMITTING DISPLAY DEVICE INCLUDING THE SAME

    -

    Paragraph 0069; 0072; 0073, (2020/07/16)

    The disclosure provides a delayed fluore...

    ORGANIC LIGHT EMITTING DEVICE

    -

    Paragraph 0152; 0152-0155, (2019/07/23)

    The present invention relates to an orga...

    Spirofluorenexanthenyl derivatives and organic electroluminescent device including the same

    -

    Paragraph 0099; 0100; 0101; 0102, (2018/07/30)

    The present invention provides an organi...

    899422-06-1 Process route

    2-bromofluoren-9-one
    3096-56-8

    2-bromofluoren-9-one

    phenol
    108-95-2,27073-41-2

    phenol

    2-bromo-spiro[fluorene-9,9′-xanthene]
    899422-06-1

    2-bromo-spiro[fluorene-9,9′-xanthene]

    Conditions
    Conditions Yield
    In methanesulfonic acid; at 152 ℃; for 24h; Inert atmosphere;
    90%
    With trichlorophosphate; at 120 ℃;
    87%
    With trichlorophosphate; at 120 ℃;
    87%
    With trichlorophosphate; at 120 ℃;
    87%
    With methanesulfonic acid; at 150 ℃; for 12h; Inert atmosphere;
    77%
    With methanesulfonic acid; at 150 ℃; for 8h;
    75%
    With methanesulfonic acid; at 150 ℃; for 24h;
    72%
    With methanesulfonic acid; for 20h; Reflux;
    71%
    With methanesulfonic acid; at 150 ℃; for 8h; Inert atmosphere;
    60%
    With methanesulfonic acid; at 150 ℃; for 8h; Inert atmosphere;
    60%
    With methanesulfonic acid; at 160 ℃; for 12h;
    55%
    With methanesulfonic acid; at 150 ℃; Inert atmosphere;
    C<sub>25</sub>H<sub>17</sub>BrO<sub>2</sub>

    C25H17BrO2

    2-bromo-spiro[fluorene-9,9′-xanthene]
    899422-06-1

    2-bromo-spiro[fluorene-9,9′-xanthene]

    Conditions
    Conditions Yield
    With hydrogenchloride; acetic acid; In water; at 75 ℃; for 6h;
    45 g

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    Purity:99%

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