1-Phenyl-3,4-dihydroisoquinoline

  • CAS:52250-50-7
  • MF:C15H13N
  • Purity:99%
  • Molecular Weight:207.275
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Product Details

  • CAS: 52250-50-7
  • MF: C15H13N
  • Manufacturer supply high quality 1-Phenyl-3,4-dihydroisoquinoline 52250-50-7 with GMP standards

    • Molecular Formula:C15H13N
    • Molecular Weight:207.275
    • Vapor Pressure:0.000408mmHg at 25°C 
    • Melting Point:174 °C 
    • Refractive Index:1.611 
    • Boiling Point:326.5 °C at 760 mmHg 
    • PKA:5.29±0.20(Predicted) 
    • Flash Point:143.4 °C 
    • PSA:12.36000 
    • Density:1.07 g/cm3 
    • LogP:2.51570 

    1-Phenyl-3,4-dihydroisoquinoline(Cas 52250-50-7) Usage

    InChI:InChI=1/C15H13N/c1-2-7-13(8-3-1)15-14-9-5-4-6-12(14)10-11-16-15/h1-9H,10-11H2

    52250-50-7 Relevant articles

    -

    Parham et al.

    , p. 1606 (1978)

    -

    Enhancement of the carbamate activation rate enabled syntheses of tetracyclic benzolactams: 8-oxoberbines and their 5- And 7-membered C-ring homologues

    Kurouchi, Hiroaki

    , p. 653 - 658 (2021/02/06)

    A route to the direct amidation of aroma...

    Tf2O/TTBP (2,4,6-Tri-tert-butylpyrimidine): An Alternative Amide Activation System for the Direct Transformations of Both Tertiary and Secondary Amides

    He, Qian,Ye, Jian-Liang,Xu, Fang-Fang,Geng, Hui,Chen, Ting-Ting,Chen, Hang,Huang, Pei-Qiang

    , (2021/09/28)

    Ten types of Tf2O/TTBP-mediated amide tr...

    Enantioselective Allylation of Cyclic and In Situ Formed N-Unsubstituted Imines with Tetraol-Protected Allylboronates

    Ullrich, Patrick,Schlamkow, Max A.,Choi, Ching-Yi,Kerkenpa?, Hannah,Hen?en, Birgit,Pietruszka, J?rg

    supporting information, p. 6254 - 6257 (2021/11/03)

    Tetraol-protected α-chiral allylboronate...

    Diprotonative stabilization of ring-opened carbocationic intermediates: conversion of tetrahydroisoquinoline to triarylmethanes

    Kurouchi, Hiroaki

    , p. 8313 - 8316 (2020/08/17)

    Superacid-promoted conversion of tetrahy...

    52250-50-7 Process route

    1-phenyl-1,2,3,4-tetrahydroisoquinoline
    22990-19-8

    1-phenyl-1,2,3,4-tetrahydroisoquinoline

    1-phenylisoquinoline
    3297-72-1

    1-phenylisoquinoline

    1-phenyl-3,4-dihydroisoquinoline
    52250-50-7

    1-phenyl-3,4-dihydroisoquinoline

    Conditions
    Conditions Yield
    With potassium phosphate tribasic trihydrate; palladium on activated charcoal; oxygen; In acetonitrile; at 60 ℃; for 17h; Solvent; Temperature; Reagent/catalyst;
    86%
    With air; In N,N-dimethyl-formamide; at 100 ℃; for 24h; Temperature; Solvent; Concentration; Schlenk technique; Green chemistry;
    83%
    With sodium carbonate; In ethyl acetate; at 120 ℃; for 24h; Overall yield = 99 %; Sealed tube; Green chemistry;
    77%
    22%
    With 1 wt % Rh0 photodeposited TiO2 nanoparticles; In isopropyl alcohol; at 20 ℃; for 48h; Irradiation; Inert atmosphere; Sealed tube;
    56%
    32%
    With oxygen; 4-amino-2,2,6,6-tetramethyl-1-piperidine-1-oxyl; In isopropyl alcohol; at 20 ℃; for 24h; under 760.051 Torr; Irradiation; Sealed tube; Sonication;
    54%
    33%
    With potassium phosphate tribasic trihydrate; 5%-palladium/activated carbon; In acetonitrile; at 60 ℃; for 22h; Reagent/catalyst; Solvent; Temperature; chemoselective reaction; Catalytic behavior; Green chemistry;
    1-phenyl-2-tosyl-1,2,3,4-tetrahydroisoquinoline

    1-phenyl-2-tosyl-1,2,3,4-tetrahydroisoquinoline

    1-phenylisoquinoline
    3297-72-1

    1-phenylisoquinoline

    1-phenyl-3,4-dihydroisoquinoline
    52250-50-7

    1-phenyl-3,4-dihydroisoquinoline

    Conditions
    Conditions Yield
    With sodium hydroxide; In water; dimethyl sulfoxide; at 125 ℃; for 2h; Inert atmosphere;
    83%
    9%

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      7-Nitro-1-(3-nitrophenyl)-3,4-dihydroisochinolin

    Antioxidant BHT 264

    CAS:128-37-0

    Purity:99%

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