What is the 2,2'-Bipyridine?

2,2'-Bipyridine is White crystalline powder, while it's Molecular Formula is C10H8N2. White crystalline powder 2,2'-bipyridine acts as a bidentate chelating ligand which form complexes with transition metal ions and shows antifungal, antibacterial and antiviral activity. It is used for the colorimetric determination of iron as well as oxidation reduction indicators to confirm the presence of ferrous ion in soils. It forms complexes with ruthenium and platinum, exhibit intense luminescence, which may have practical applications. Copper(I) bipyridine complexes involved in the oxidation of alcohols under aerobic conditions.

What is the CAS number for 2,2'-Bipyridine?

The CAS number of 2,2'-Bipyridine is 366-18-7.

What is 2,2'-Bipyridine (366-18-7) used for?

2,2'-Bipyridine, also known as 2,2'-Bipyridyl, is a symmetrical bipyridine commonly used as a neutral ligand for complexation with metal ions. It is a white to light red crystalline powder that is soluble in various organic solvents. The molecule is planar with a trans-conformation and crystallizes in the monoclinic crystal system. It has a role as a ferroptosis inhibitor and a chelator.

What is the 2,2'-Bipyridine?

2,2'-Bipyridine is White crystalline powder, while it's Molecular Formula is C10H8N2. White crystalline powder 2,2'-bipyridine acts as a bidentate chelating ligand which form complexes with transition metal ions and shows antifungal, antibacterial and antiviral activity. It is used for the colorimetric determination of iron as well as oxidation reduction indicators to confirm the presence of ferrous ion in soils. It forms complexes with ruthenium and platinum, exhibit intense luminescence, which may have practical applications. Copper(I) bipyridine complexes involved in the oxidation of alcohols under aerobic conditions.

What is the CAS number for 2,2'-Bipyridine?

The CAS number of 2,2'-Bipyridine is 366-18-7.

What is 2,2'-Bipyridine (366-18-7) used for?

2,2'-Bipyridine, also known as 2,2'-Bipyridyl, is a symmetrical bipyridine commonly used as a neutral ligand for complexation with metal ions. It is a white to light red crystalline powder that is soluble in various organic solvents. The molecule is planar with a trans-conformation and crystallizes in the monoclinic crystal system. It has a role as a ferroptosis inhibitor and a chelator.

2,2'-Bipyridine

CAS：366-18-7
MF：C₁₀H₈N₂
Purity：99%
Molecular Weight：157.195

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Product Details

CAS： 366-18-7

MF： C₁₀H₈N₂

Appearance： White crystalline powder

Chinese factory supply 2,2'-Bipyridine 366-18-7 in stock with high standard

Molecular Formula:C10H8N2
Molecular Weight:157.195
Appearance/Colour:White crystalline powder
Vapor Pressure:0.584Pa at 25℃
Melting Point:70-73 °C(lit.)
Refractive Index:1.4820 (estimate)
Boiling Point:272.499 °C at 760 mmHg
PKA:pK1:-0.52(+2);pK2:4.352(+1) (20°C)
Flash Point:107.243 °C
PSA：25.78000
Density:1.106 g/cm³
LogP:2.14360

366-18-7 Relevant articles

INVESTIGATION OF THE INTERACTION OF PYRIDINE WITH THE SURFACE OF LAMINAR SILICATES BY THE METHOD OF OPTICAL ELECTRONIC SPECTROSCOPY.

Sivalov,Tarasevich

, p. 214 - 218 (1981)

A study of the nature of the active site...

General Method for Synthesis of Bipyridines: Palladium Catalyzed Cross-coupling Reaction of Trimethylstannylpyridines with Bromopyridines

Yamamoto, Yutaka,Azuma, Yutaka,Mitoh, Hiroyuki

, p. 564 - 565 (1986)

Trimethylstannylpyridines 1 were treated...

Mild and efficient formation of symmetric biaryls via Pd(II) catalysts and Cu(II) oxidants

Parrish, Jay P.,Flanders, Vincent L.,Floyd, Ryan J.,Jung, Kyung Woon

, p. 7729 - 7731 (2001)

Described herein is a mild and efficient...

-

Dearmond et al.

, p. 3388,3391 (1979)

-

Brown,Ahmad

, p. 3485,3487 (1972)

Cation-Assisted Ligand Photosubstitution in Transition-Metal Complexes. Photoreactions of Ru(bpy)32+ with Ag+ in Acetonitrile

Foreman, T. K.,Bonilha, J. B. S.,Whitten, D. G.

, p. 3436 - 3439 (1982)

Irradiation of Ru(bpy)32+ in the presenc...

Photoactivatable RuII Complex Bearing 2,9-Diphenyl-1,10-phenanthroline: Unusual Photochemistry and Significant Potency on Cisplatin-Resistant Cell Lines

Mansour, Najwa,Mehanna, Stephanie,Mroueh, Mohamad A.,Audi, Hassib,Bodman-Smith, Kikki,Daher, Costantine F.,Taleb, Robin I.,El-Sibai, Mirvat,Khnayzer, Rony S.

, p. 2524 - 2532 (2018)

The current study investigates [Ru(bipy)...

Acid directed in situ oxidation and decarboxylation of 4,4′,6, 6′-tetra-methyl-2,2′-bipyridine: Synthesis and structural characterisation of 4,4′,6-tri-carboxy-2,2′-bipyridine and its copper(II) coordination polymer

Kelly, Niamh R.,Goetz, Sandrine,Hawes, Chris S.,Kruger, Paul E.

, p. 102 - 109 (2013)

The reaction of either 4,4′,6,6′-tetrame...

Excited state dynamics of organo-lanthanide electroluminescent phosphors: The properties of Tb(tb-pmp)3 and Gd(tb-pmp)3

Thorne,Rey,Denning,Watkins,Etchells,Green,Christou

, p. 4014 - 4021 (2002)

The excitation energy transfer rates bet...

DIMER FORMATION IN THE REACTION OF ARYL HALIDES CATALYZED BY NICKEL COMPLEXES

Budnikova, Yu. G.,Kargin, Yu. M.,Yanilkin, V. V.

, p. 1299 - 1300 (1992)

The synthesis of diaryls catalyzed by el...

The use of Ni(CO)2(PPh3)2 in aryl and pyridyl coupling reactions

Leadbeater, Nicholas E.,Resouly, Sarah M.

, p. 4243 - 4246 (1999)

The zerovalent nickel complex Ni(CO)2(PP...

Phototoxicity of strained Ru(II) complexes: Is it the metal complex or the dissociating ligand?

Azar, Daniel F.,Audi, Hassib,Farhat, Stephanie,El-Sibai, Mirvat,Abi-Habib, Ralph J.,Khnayzer, Rony S.

, p. 11529 - 11532 (2017)

A photochemically dissociating ligand in...

Ligand-free Stille cross-coupling reaction using Pd/CaCO3 as catalyst reservoir

Coelho, Aline V.,de Souza, Andréa Luzia F.,de Lima, Paulo G.,Wardell, James L.,Antunes

, p. 7671 - 7674 (2007)

Stille reactions between halobenzenes an...

Novel synthesis method of 2, 2 '-dipyridyl

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Paragraph 0017-0020, (2021/03/10)

The invention discloses a novel synthesi...

Pincerlike manganese complex and preparation method thereof, related ligand and preparation method thereof, catalyst composition and application

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Paragraph 0159-0165, (2021/07/31)

The invention discloses a pincerlike man...

Highly Chemoselective Deoxygenation of N-Heterocyclic N-Oxides Using Hantzsch Esters as Mild Reducing Agents

An, Ju Hyeon,Kim, Kyu Dong,Lee, Jun Hee

supporting information, p. 2876 - 2894 (2021/02/01)

Herein, we disclose a highly chemoselect...

Pd-catalyzed oxidative homocoupling of arylboronic acids in WEPA: A sustainable access to symmetrical biaryls under added base and ligand-free ambient conditions

Appa, Rama Moorthy,Lakshmidevi, Jangam,Naidu, Bandameeda Ramesh,Venkateswarlu, Katta

, (2021/01/11)

Symmetrical and unsymmetrical biaryls co...

366-18-7 Process route

: 17099-99-9
tetrachloro-2,2'-bipyridylzirconium

: 366-18-7
[2,2]bipyridinyl

: 10026-11-6
zirconium(IV) chloride

Conditions

Conditions	Yield
In neat (no solvent); heating under N2 above 400 °C;

: [Mn4(μ-O)6(2,2'-bipyridine)6][ClO4]4*H2O

: 7803-49-8
hydroxylamine

: hydrogen cation

: 366-18-7
[2,2]bipyridinyl

: 7732-18-5
water

: 16397-91-4
manganese(II)

: 10024-97-2
dinitrogen monoxide