What is the 2-Carboxybenzaldehyde?

2-Carboxybenzaldehyde is white crystal powder, while it's Molecular Formula is C8H6O3. white crystal powder 2-Carboxybenzaldehyde is a carboxylated derivative of benzaldehyde which is readily converted to 2-hydroxymethyl benzoic acid by CBA dehydrogenase. 2-Carboxybenzaldehyde is a metabolite of ampicillin phthalidyl ester. It has been used to synthesize a series of N-substituted isoindolinones by reductive C-N coupling and intramolecular amidation with amines.

What is the CAS number for 2-Carboxybenzaldehyde?

The CAS number of 2-Carboxybenzaldehyde is 119-67-5.

What is 2-Carboxybenzaldehyde (119-67-5) used for?

2-Carboxybenzaldehyde, also known as benzoic aldehyde, is an aldehydic acid derived from benzoic acid with a formyl group substitution at the 2nd position. It is a white to slightly beige crystalline powder and is a metabolite of ampicillin phthalidyl ester. This carboxylated derivative of benzaldehyde is known for its versatile chemical properties and potential applications in various industries.InChI:InChI=1/C8H6O3/c9-5-6-3-1-2-4-7(6)8(10)11/h1-5H,(H,10,11)/p-1

What is the 2-Carboxybenzaldehyde?

2-Carboxybenzaldehyde is white crystal powder, while it's Molecular Formula is C8H6O3. white crystal powder 2-Carboxybenzaldehyde is a carboxylated derivative of benzaldehyde which is readily converted to 2-hydroxymethyl benzoic acid by CBA dehydrogenase. 2-Carboxybenzaldehyde is a metabolite of ampicillin phthalidyl ester. It has been used to synthesize a series of N-substituted isoindolinones by reductive C-N coupling and intramolecular amidation with amines.

What is the CAS number for 2-Carboxybenzaldehyde?

The CAS number of 2-Carboxybenzaldehyde is 119-67-5.

What is 2-Carboxybenzaldehyde (119-67-5) used for?

2-Carboxybenzaldehyde, also known as benzoic aldehyde, is an aldehydic acid derived from benzoic acid with a formyl group substitution at the 2nd position. It is a white to slightly beige crystalline powder and is a metabolite of ampicillin phthalidyl ester. This carboxylated derivative of benzaldehyde is known for its versatile chemical properties and potential applications in various industries.InChI:InChI=1/C8H6O3/c9-5-6-3-1-2-4-7(6)8(10)11/h1-5H,(H,10,11)/p-1

2-Carboxybenzaldehyde

CAS：119-67-5
MF：C₈H₆O₃
Purity：99%
Molecular Weight：150.134

Get the best price

Product Details

CAS： 119-67-5

MF： C₈H₆O₃

Appearance： white crystal powder

Quality Manufacturer Supply High Purity 99% 2-Carboxybenzaldehyde 119-67-5 with Reasonable Price

Molecular Formula:C8H6O3
Molecular Weight:150.134
Appearance/Colour:white crystal powder
Vapor Pressure:0.00012mmHg at 25°C
Melting Point:94-96 °C(lit.)
Refractive Index:1.4500 (estimate)
Boiling Point:321.8 °C at 760 mmHg
PKA:4.57±0.10(Predicted)
Flash Point:162.6 °C
PSA：54.37000
Density:1,404 g/cm³
LogP:1.19730

2-Carboxybenzaldehyde(Cas 119-67-5) Usage

Synthesis Reference(s)	Tetrahedron Letters, 14, p. 3535, 1973 DOI: 10.1016/S0040-4039(01)86963-XThe Journal of Organic Chemistry, 32, p. 3200, 1967 DOI: 10.1021/jo01285a061
Definition	ChEBI: An aldehydic acid which consists of benzoic acid substituted by a formyl group at position 2.

InChI:InChI=1/C8H6O3/c9-5-6-3-1-2-4-7(6)8(10)11/h1-5H,(H,10,11)/p-1

119-67-5 Relevant articles

Synthetic application of lithiation reactions. IX. A simplified synthesis of isocoumarin

Narasimhan,Mali

, p. 797 - 797 (1975)

-

Sturrock,M.G. et al.

, p. 3047 - 3051 (1971)

-

Matsuura et al.

, p. 6149,6154 (1968)

Prevention of manganese precipitation during the continuous selective partial oxidation of methyl aromatics with molecular oxygen in supercritical water

Fraga-Dubreuil, Joan,Garcia-Verdugo, Eduardo,Hamley, Paul A.,Perez, Eduardo,Pearson, Ian,Thomas, W. Barry,Housley, Duncan,Partenheimer, Walt,Poliakoff, Martyn

, p. 1866 - 1876 (2009)

Presented here is an investigation of th...

-

Cava et al.

, p. 2947 (1964)

-

Cava et al.

, p. 2076,2079 (1963)

-

Sidgwick,Clayton

, p. 2263 Anm. (1922)

-

Cava,Napier

, p. 3606 (1957)

-

Dahlgren,Schell

, p. 3200 (1967)

Selectivity in catalytic diol electrooxidation using a polypyridine ru(iv) complex

Navarro, Marcelo,De Giovani, Wagner F.,Romero, Jose R.

, p. 851 - 857 (1991)

1,2-, 1,3-, and 1,4-Butanediols and phth...

-

Maekawa,Sumimoto

, p. 941,942 (1960)

Facile construction of pyrrolo[1,2-: B] isoquinolin-10(5 H)-ones via a redox-amination-aromatization-Friedel-Crafts acylation cascade reaction and discovery of novel topoisomerase inhibitors

Wu, Shanchao,Liu, Na,Dong, Guoqiang,Ma, Lin,Wang, Shengzheng,Shi, Wencai,Fang, Kun,Chen, Shuqiang,Li, Jian,Zhang, Wannian,Sheng, Chunquan,Wang, Wei

, p. 9593 - 9596 (2016)

An efficient redox-amination-aromatizati...

Oxidation of benzyl alcohol by pyridinium dichromate in acetonitrile. Using the paralmeta ratio of substituent effects for mechanism elucidation

Kabilan,Girija,Reis, Joao Carlos R.,Segurado, Manuel A.P.,De Oliveira, Jaime D. Gomes

, p. 1151 - 1157 (2002)

Rate constants were measured for the oxi...

Industrial synthesis method of o-aldehyde phenyl fatty acid

-

, (2020/01/08)

The invention provides an industrial syn...

Synthesis method of O-formyl benzoic acid

-

Paragraph 0009 0011-0012, (2019/12/25)

The invention discloses a synthesis meth...

Synthesis of chiral isoindolinones via asymmetric propargylation/lactamization cascade

Meng, Jiao-Long,Jiao, Tang-Qian,Chen, Ya-Heng,Fu, Rui,Zhang, Shu-Sheng,Zhao, Qian,Feng, Chen-Guo,Lin, Guo-Qiang

supporting information, p. 1564 - 1567 (2018/03/23)

A Zn-mediated propargylation/lactamizati...

Cu/Fe Catalyzed Intermolecular Oxidative Amination of Benzylic C-H Bonds

Liu, Cong,Zhang, Qi,Li, Hongbo,Guo, Shuangxi,Xiao, Bin,Deng, Wei,Liu, Lei,He, Wei

supporting information, p. 6208 - 6212 (2016/05/09)

We report a Cu/Fe co-catalyzed Ritter-ty...

119-67-5 Process route

: 95-47-6
o-xylene

: 118-90-1
ortho-methylbenzoic acid

: 612-20-4
2-(hydroxymethyl)benzoic acid

: 88-99-3,73607-73-5
benzene-1,2-dicarboxylic acid

: 119-67-5
o-carboxybenzaldehyde

Conditions

Conditions	Yield
o-xylene; With N-hydroxyphthalimide; air; cobalt(II) acetate; manganese(II) acetate; In acetic acid; at 150 ℃; for 3h; under 22801.5 Torr; With sodium hydroxide; at 90 ℃; Further stages.;	73% 6% 8% 3%

: 95-47-6
o-xylene

: 118-90-1
ortho-methylbenzoic acid

: 124-38-9,18923-20-1
carbon dioxide

: 612-20-4
2-(hydroxymethyl)benzoic acid

: 88-99-3,73607-73-5
benzene-1,2-dicarboxylic acid

: 65-85-0,8013-63-6
benzoic acid

: 119-67-5
o-carboxybenzaldehyde

Conditions

Conditions	Yield
With water; hydrogen bromide; dihydrogen peroxide; at 380 ℃; under 172517 Torr;	58.6 mol % 15.2 mol %

119-67-5 Upstream products

6940-49-4
3-Bromophthalide
612-40-8
2-carboxycinnamic acid
528-46-1
phthalonic acid
64148-19-2
2-dichloromethyl-benzonitrile

119-67-5 Downstream products

4195-21-5
3-morpholin-4-yl-3H-isobenzofuran-1-one
6936-87-4
3-(1H-indol-3-yl)isobenzofuran-1(3H)-one
73973-01-0
2-Methyl-3-phthalidyl-indol
56661-83-7
2-(4-oxo-2-thioxo-thiazolidin-5-ylidenemethyl)-benzoic acid

Relevant Products

4,4’-BPS
CAS：80-09-1
Get the best price
5A-Hydroxy Laxogenin
CAS：56786-63-1
Get the best price
Antioxidant TMQ
CAS：26780-96-1
Get the best price
Antioxidant 6PPD
CAS：793-24-8
Get the best price

2-Carboxybenzaldehyde

Quality Manufacturer Supply High Purity 99% 2-Carboxybenzaldehyde 119-67-5 with Reasonable Price

2-Carboxybenzaldehyde(Cas 119-67-5) Usage

119-67-5 Relevant articles

Synthetic application of lithiation reactions. IX. A simplified synthesis of isocoumarin

Narasimhan,Mali

, p. 797 - 797 (1975)

-

Sturrock,M.G. et al.

, p. 3047 - 3051 (1971)

-

Matsuura et al.

, p. 6149,6154 (1968)

Prevention of manganese precipitation during the continuous selective partial oxidation of methyl aromatics with molecular oxygen in supercritical water

Fraga-Dubreuil, Joan,Garcia-Verdugo, Eduardo,Hamley, Paul A.,Perez, Eduardo,Pearson, Ian,Thomas, W. Barry,Housley, Duncan,Partenheimer, Walt,Poliakoff, Martyn

, p. 1866 - 1876 (2009)

-

Cava et al.

, p. 2947 (1964)

-

Cava et al.

, p. 2076,2079 (1963)

-

Sidgwick,Clayton

, p. 2263 Anm. (1922)

-

Cava,Napier

, p. 3606 (1957)

-

Dahlgren,Schell

, p. 3200 (1967)

Selectivity in catalytic diol electrooxidation using a polypyridine ru(iv) complex

Navarro, Marcelo,De Giovani, Wagner F.,Romero, Jose R.

, p. 851 - 857 (1991)

-

Maekawa,Sumimoto

, p. 941,942 (1960)

Facile construction of pyrrolo[1,2-: B] isoquinolin-10(5 H)-ones via a redox-amination-aromatization-Friedel-Crafts acylation cascade reaction and discovery of novel topoisomerase inhibitors

Wu, Shanchao,Liu, Na,Dong, Guoqiang,Ma, Lin,Wang, Shengzheng,Shi, Wencai,Fang, Kun,Chen, Shuqiang,Li, Jian,Zhang, Wannian,Sheng, Chunquan,Wang, Wei

, p. 9593 - 9596 (2016)

Oxidation of benzyl alcohol by pyridinium dichromate in acetonitrile. Using the paralmeta ratio of substituent effects for mechanism elucidation

Kabilan,Girija,Reis, Joao Carlos R.,Segurado, Manuel A.P.,De Oliveira, Jaime D. Gomes

, p. 1151 - 1157 (2002)

Industrial synthesis method of o-aldehyde phenyl fatty acid

-

, (2020/01/08)

Synthesis method of O-formyl benzoic acid

-

Paragraph 0009 0011-0012, (2019/12/25)

Synthesis of chiral isoindolinones via asymmetric propargylation/lactamization cascade

Meng, Jiao-Long,Jiao, Tang-Qian,Chen, Ya-Heng,Fu, Rui,Zhang, Shu-Sheng,Zhao, Qian,Feng, Chen-Guo,Lin, Guo-Qiang

supporting information, p. 1564 - 1567 (2018/03/23)

Cu/Fe Catalyzed Intermolecular Oxidative Amination of Benzylic C-H Bonds

Liu, Cong,Zhang, Qi,Li, Hongbo,Guo, Shuangxi,Xiao, Bin,Deng, Wei,Liu, Lei,He, Wei

supporting information, p. 6208 - 6212 (2016/05/09)

119-67-5 Process route

119-67-5 Upstream products

119-67-5 Downstream products

Relevant Products

Antioxidant BHT 264

Contact Now