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9-Bromophenanthrene

  • CAS:573-17-1
  • MF:C14H9Br
  • Purity:99%
  • Molecular Weight:257.129
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Product Details

  • CAS: 573-17-1
  • MF: C14H9Br
  • Appearance: yellow cystalline powder
  • Chinese Factory Supply Wholesale 9-Bromophenanthrene 573-17-1 with Cheap Price

    • Molecular Formula:C14H9Br
    • Molecular Weight:257.129
    • Appearance/Colour:yellow cystalline powder 
    • Melting Point:60-64 °C(lit.) 
    • Refractive Index:1.6404 (estimate) 
    • Boiling Point:389.7 °C at 760 mmHg 
    • Flash Point:190.3 °C 
    • PSA:0.00000 
    • Density:1.479 g/cm3 
    • LogP:4.75550 

    9-Bromophenanthrene(Cas 573-17-1) Usage

    Preparation

    9-Bromophenanthrene (90-94%) is produced by adding bromine to a refluxing solution of phenanthrene in carbon tetrachloride. This is the starting-point of 9-substituted phenanthrenes, e.g, when heated with cuprous cyanide at 260℃, 9-bromophenanthrene forms the corresponding cyano-compound; this may be hydrolysed to phenanthrene-9-carboxylic acid. Phenanthrene undergoes the Friedel-Crafts reaction mainly in the 3-, and to a small extent, in the 2-position. It is chloromethylated in the 9-position. When nitrated, phenanthrene gives a mixture of three mononitro-derivatives, the 3-isomer predominating. Sulphonation of phenanthrene gives a mixture of 1-, 2-, 3- and 9-phenanthrenesulphonic acids, and the ratio of these isomers depends on the temperature.

    InChI:InChI=1/C14H9Br/c15-14-9-10-5-1-2-6-11(10)12-7-3-4-8-13(12)14/h1-9H

    573-17-1 Relevant articles

    A simple Hückel model-driven strategy to overcome electronic barriers to retro-Brook silylation relevant to aryne and bisaryne precursor synthesis

    Neal, Edward A.,Werling,Jones, Christopher R.

    supporting information, p. 1663 - 1666 (2021/02/26)

    ortho-Silylaryl triflate precursors (oSA...

    Preparation method of 9-hydroxyphenanthrene

    -

    Paragraph 0045-0046; 0049-0050, (2021/08/07)

    The invention discloses a preparation me...

    Chiral Ligand-Mediated Nucleophilic Aromatic Substitution of Naphthoic Acids: A Fast and Efficient Access to Axially Chiral Biaryls

    Nguyen, Thi Thanh Thuy,Guyon, Hélène,Nguyen, Kim Phi Phung,Boussonnière, Anne,Mortier, Jacques,Castanet, Anne-Sophie

    supporting information, p. 3829 - 3833 (2020/05/25)

    A transition metal-free synthesis of ena...

    Regioselective arene homologation through rhenium-catalyzed deoxygenative aromatization of 7-oxabicyclo[2.2.1]hepta-2,5-dienes

    Murai, Masahito,Ogita, Takuya,Takai, Kazuhiko

    supporting information, p. 2332 - 2335 (2019/02/27)

    Combined use of oxorhenium catalysts wit...

    573-17-1 Process route

    9,10-dibromo-9,10-dihydro-phenanthrene
    17533-18-5

    9,10-dibromo-9,10-dihydro-phenanthrene

    9-bromophenanthrene
    573-17-1

    9-bromophenanthrene

    hydrogen bromide
    10035-10-6,12258-64-9

    hydrogen bromide

    Conditions
    Conditions Yield
    beim Erhitzen fuer sich;
    9,10-dibromo-9,10-dihydro-phenanthrene
    17533-18-5

    9,10-dibromo-9,10-dihydro-phenanthrene

    water
    7732-18-5

    water

    9-bromophenanthrene
    573-17-1

    9-bromophenanthrene

    hydrogen bromide
    10035-10-6,12258-64-9

    hydrogen bromide

    Conditions
    Conditions Yield
    im geschlossenen Rohr;

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