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TATM

  • CAS：92051-23-5
  • MF：C15H19F3O12S
  • Purity：99%
  • Molecular Weight：480.37
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Product Details

  • CAS： 92051-23-5
  • MF： C15H19F3O12S
  • Appearance： Beige crystal

    • Manufacturer supply good quality TATM 92051-23-5 with stock

    • Molecular Formula:C15H19F3O12S
    • Molecular Weight:480.37
    • Appearance/Colour:Beige crystal 
    • Vapor Pressure:0mmHg at 25°C 
    • Melting Point:118-122 °C 
    • Refractive Index:-16 ° (C=1, CHCl3) 
    • Boiling Point:481.597 °C at 760 mmHg 
    • Flash Point:245.061 °C 
    • PSA：166.18000 
    • Density:1.505 g/cm3 
    • LogP:1.01650 

    TATM(Cas 92051-23-5) Usage

    Physical properties

    White to off-white powder or crystal

    InChI:InChI=1/C15H19F3O12S/c1-6(19)25-5-10-11(26-7(2)20)12(27-8(3)21)13(14(29-10)28-9(4)22)30-31(23,24)15(16,17)18/h10-14H,5H2,1-4H3/t10-,11-,12+,13+,14-/m1/s1

    92051-23-5 Relevant articles

    Design and synthesis of substrate-mimic inhibitors of mycothiol-S-conjugate amidase from Mycobacterium tuberculosis

    Metaferia, Belhu B.,Ray, Satyajit,Smith, Jeremy A.,Bewley, Carole A.

    , p. 444 - 447 (2007)

    The Staudinger reaction between a polyme...

    Synthesis, photophysical properties, and photodynamic activity of positional isomers of TFPP-glucose conjugates

    Fadlan, Arif,Tanimoto, Hiroki,Ito, Tatsuya,Aritomi, Yusuke,Ueno, Maho,Tokuda, Masaya,Hirohara, Shiho,Obata, Makoto,Morimoto, Tsumoru,Kakiuchi, Kiyomi

    supporting information, p. 1848 - 1858 (2018/03/06)

    The synthesis and characterization of a ...

    3,4,6-Tri-O-acetyl-1,2-O-[1-(exo-ethoxy)ethyl-idene]-Β-d-manno- pyranose 0.11-hydrate

    Liu, Ya-Ling,Zou, Pei,Wu, Hao,Xie, Min-Hao,Luo, Shi-Neng

    , p. o338-o340 (2012/11/13)

    The title compound, C16H24O10·0. 11H2O, ...

    A biosynthetic pathway for BE-7585A, a 2-thiosugar-containing angucycline-type natural product

    Sasaki, Eita,Ogasawara, Yasushi,Liu, Hung-Wen

    experimental part, p. 7405 - 7417 (2010/08/05)

    Sulfur is an essential element found ubi...

    Synthesis of the positron-emitting radiotracer [18F]-2-fluoro-2- deoxy-d-glucose from resin-bound perfluoroalkylsulfonates

    Brown, Lynda J.,Ma, Nianchun,Bouvet, Denis R.,Champion, Sue,Gibson, Alex M.,Hu, Yulai,Jackson, Alex,Khan, Imtiaz,Millot, Nicolas,Topley, Amy C.,Wadsworth, Harry,Wynn, Duncan,Brown, Richard C. D.

    scheme or table, p. 564 - 575 (2009/07/18)

    A new approach to the synthesis of 2-flu...

    92051-23-5 Process route

    trifluoromethylsulfonic anhydride
    358-23-6

    trifluoromethylsulfonic anhydride

    1,3,4,6-tetra-O-acetyl-β-D-mannopyranose
    18968-05-3

    1,3,4,6-tetra-O-acetyl-β-D-mannopyranose

    1,3,4,6-tetra-O-acetyl-2-O-trifluoromethanesulfonyl-β-D-mannopyranose
    92051-23-5

    1,3,4,6-tetra-O-acetyl-2-O-trifluoromethanesulfonyl-β-D-mannopyranose

    Conditions
    Conditions Yield
    With pyridine; In dichloromethane; -15 deg C to 5 deg C;
    		97.5%
    With pyridine; In dichloromethane; at -20 - 20 ℃; for 2h; Inert atmosphere;
    		96%
    With pyridine; In dichloromethane; at -20 - -10 ℃;
    		93%
    With pyridine; In dichloromethane; at -15 - 20 ℃; Inert atmosphere;
    		90%
    In pyridine; dichloromethane; for 1h; Ambient temperature;
    		60%
    With pyridine; In dichloromethane; at -15 - 20 ℃; Inert atmosphere;
    		56%
    With pyridine;
    With pyridine; In dichloromethane;
    With pyridine;
    1,3,4,6-tetra-O-acetyl-β-D-mannopyranose
    18968-05-3

    1,3,4,6-tetra-O-acetyl-β-D-mannopyranose

    1,3,4,6-tetra-O-acetyl-2-O-trifluoromethanesulfonyl-β-D-mannopyranose
    92051-23-5

    1,3,4,6-tetra-O-acetyl-2-O-trifluoromethanesulfonyl-β-D-mannopyranose

    Conditions
    Conditions Yield
    With pyridine; trifluoromethanesulfonic acid anhydride; In dichloromethane;
    		1.59 g (77%)

    92051-23-5 Upstream products

    • 358-23-6
      358-23-6

      trifluoromethylsulfonic anhydride

    • 18968-05-3
      18968-05-3

      1,3,4,6-tetra-O-acetyl-β-D-mannopyranose

    • 83-87-4
      83-87-4

      D-Mannose pentaacetate

    • 28140-37-6
      28140-37-6

      3,4,6-tri-O-acetyl-1,2-O-(1-ethoxyethylidene)-β-D-mannopyranoside

    92051-23-5 Downstream products

    • 13992-25-1
      13992-25-1

      1-azido-1-deoxy-β-D-glucopyranoside tetraacetate

    • 105851-17-0
      105851-17-0

      2-deoxy-2-[18F]fluoro-D-glucopyranose

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    Antioxidant BHT 264

    CAS:128-37-0

    Purity:99%

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